Functionality
AWS Managed Service
Something you can monitor in AWS
How to monitor a homegrown solution
AWS Simple Email Service (SES)
All available metrics are listed here, including bounce and compliance rate
To monitor bounce rate you would either need to use a third party mailing service or manually track email bounces in your application
AWS Simple Storage Service (S3)
All available metrics are listed here, including size of bucket and # of items in the bucket
To monitor something such as # of items in the bucket you would need to either keep a small database up to date, continuously pull the number of stored items, or use a third party service.
AWS Application Load Balancer (ALB)
All available metrics are listed here, including 5xx errors and 4xx errors
On a home grown Load Balancer you would need to use custom plugins (such as the Datadog integration for HAProxy) and a custom solution to store the metrics, or to process the logs to create your own metrics.